Phase formation in ion irradiated metal-organic complexes of copper-bis-acetylacetonate
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CONTRIBUTORS:
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JOURNAL:
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phys. stat. sol. (a),
196(2),
405 -
409.
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YEAR:
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2003
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PUB TYPE:
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Journal Article
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SUBJECT(S):
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CuO, ion irradiation, chelates, phase formation
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DISCIPLINE:
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Physics
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HTTP:
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http://DOI 10.1002/pssa.200305954
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LANGUAGE:
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English
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PUB ID:
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103-445-505
(Last edited on
2008/10/07 02:54:23 GMT-6)
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SPONSOR(S):
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ABSTRACT:
Irradiation effects on spin cast films of metal-organic copper-bis-acetylacetone [((CH3CO)2CH)2Cu:Cu(acac)2] have been studied using He+, Ar+, and O+ ionic species. The formation of CuO and paramelaconite (6CuO · Cu2O) phases is observed in the irradiated samples irrespectively of the
ionic species. Post irradiation oxygen annealing leads to the formation of a single phase CuO film for the
sample irradiated with O+ ions. The formation of a single phase CuO film is assigned to the combination
of the fact that the compound formations with higher oxidation states are preferred
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